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NMFC 45463 - Organic Peroxides, NOI | Class N/A

Article ID
45463
NMFC 45463 Organic Peroxides, NOI reference item
Freight Group
CHEMICALS GROUP
Chemicals Group hazmat handling and paperwork
Class Range
N/A 0 classification
Class not listed here, see Note 45464
Hazardous
Yes
Hazardous, DOT Class 5.2 oxidizing peroxide

Classification Details

NMFC Description Class
45463.00 Organic Peroxides, NOI, see Note, item 45464, in U.S. DOT-authorized packaging:

Notes

Note 45464: NOTE-Applies on materials regulated by the U.S. Department of Transportation as a Hazard Class 5, Division 5.2, Organic Peroxide, as defined in 49 CFR 173.128 and required to bear a notice to that effect on bills of lading and packaging.

How to Determine Your Class

To find the correct freight class for your shipment:

  1. Confirm your product’s exact UN identification and SDS, then match it to Note item 45464 before tendering under NMFC 45463 to ensure the correct sub-item.
  2. Use only U.S. DOT-authorized inner/outer packagings for organic peroxides; verify closure instructions and UN marks on cartons and overpacks.
  3. Maintain carrier-required hazmat documentation: proper shipping name for the specific type, emergency contact info, and Class 5.2 labels plus orientation marks if liquids.
  4. Plan handling and segregation: keep away from combustibles, acids, and reducing agents, and request temperature protection if the SDS flags heat sensitivity.

Note: All classifications are subject to Item 170. Verify with official NMFC publications for the most current requirements.

Business Value

  • Accurate use of NMFC 45463 and the 45464 note reduces reclassification fees and billing disputes tied to hazmat entries.
  • DOT-authorized packaging and correct hazard marking speed carrier acceptance, minimizing terminal delays and reship costs.
  • Selecting the precise sub-item via Note 45464 can influence rates and surcharges, improving your landed cost on LTL lanes.
  • Proper declaration and segregation lower claim exposure and regulatory penalties, protecting on-time performance and customer SLAs.